Research Activities of Sottmann Group

Enhanced Oil Recovery

Utilization of super-critical CO₂ in oil recovery

Overview

This topic deals with the study of Enhanced Oil Recovery (EOR) methods, particularly CO2 flooding and surfactant flooding processes. Beside extensive phase behavior studies under typical reservoir conditions (1-400 bar and 5-80°C), the structures of these systems are investigated by scattering methods, e.g. SLS, DLS, SAXS and SANS.

CO2 injection is a technique used for recovering residual oil from mature reservoirs [1]. It gains more and more interest due to the importance of carbon dioxide capturing and sequestration. In most reservoirs, CO2 is in a supercritical state (scCO2). The swelling of crude oil by scCO2, and consequently the efficiency of a flood, strongly depends on the miscibility of crude oil and solvent. Therefore, immiscibility of scCO2 with crude oil leads to poor recovery, which poses some limitations to CO2 EOR procedures. Additionally, viscosity or gravity effects could decrease the sweep efficiency and therewith the recovery rate. The miscibility of scCO2 and crude oil can be improved by solubilizing an appropriate additive in the scCO2. In this project, the compatibility of different additives with scCO2 is investigated in order to identify compounds that enable an easy co-injection of the additive within the flow of the CO2. Therefore, phase behavior studies under typical reservoir pressures and temperatures with a (model) crude oil are performed in a home-made high-pressure cell [2].

Scheme of EOR CO₂ flooding and sketch of high-pressure cell (c)
Figure 1: (Left) Scheme of EOR CO₂ flooding [1] (Right) Technical sketch of the home-made high pressure cell designed for the phase behavior studies [2]..

Another promising EOR method is the “surfactant flooding” process (Fig. 2), which plays an important role due to the outstanding ability of surfactants to reduce the interfacial tension between oil and water and to improve the wettability of reservoir rocks [3]. In a systematic study, microemulsions containing pure n-alkanes ranging from medium-chain oils (e.g. n-dodecane) to pure long-chain oils (e.g. n-dotriacontane) or even technical-grade waxes (e.g. SASOLWAX 5805) became possible using both pure and technical-grade non-ionic n-alkyl polyglycol ether (CiEj)-type surfactants [4]. In an ongoing project, other technical water-based microemulsions are studied to elucidate the effect of pressure, temperature, salt concentration, and the length of n-alkanes on the phase behavior of these systems. The model of Salager [5] is subsequently applied to predict the optimal state of the candidate microemulsion system.

Scheme of surfactant flooding (c)
Figure 2: Two-dimensional schematic diagram of surfactant flooding [3].

References

  1. Rommerskirchen, R., Bilgili, H., Fischer, J., Sottmann, T.: Impact of Miscibility Enhancing Additives on the Flooding Scheme in CO2 EOR Processes. In: SPE Improved Oil Recovery Conference. pp. 12-. Society of Petroleum Engineers, Tulsa, Oklahoma, USA (2018).
  2. Schwan, M., Kramer, L. G. A., Sottmann, T., Strey, R.: Phase behaviour of propane- and scCO2-microemulsions and their prominent role for the recently proposed foaming procedure POSME (Principle of Supercritical Microemulsion Expansion). Phys. Chem. Chem. Phys. 12, 6247-6252 (2010). https://doi.org/10.1039/B909764C
  3. Bera, A., Mandal, A. J.: Microemulsions: a novel approach to enhanced oil recovery: a review. Petrol. Explor. Prod. Technol. 5, 255-268 (2015). https://doi.org/10.1007/s13202-014-0139-5
  4. Schneider, K., Ott, T. M., Schweins, R., Frielinghaus, H., Lade, O., Sottmann, T.: Phase Behavior and Microstructure of Symmetric Nonionic Microemulsions with Long-Chain n-Alkanes and Waxes. Industrial & Engineering Chemistry Research. 58, 2583–2595 (2019). https://doi.org/10.1021/acs.iecr.8b04833 
  5. Salager, J.-L., Forgiarini, A. M., Bullón, J.: How to Attain Ultralow Interfacial Tension and Three-Phase Behavior with Surfactant Formulation for Enhanced Oil Recovery: A Review. Part 1. Optimum Formulation for Simple Surfactant–Oil–Water Ternary Systems. J. Surfact. Deterg. 16, 449-472 (2013). https://doi.org/10.1007/s11743-013-1470-4

Cooperations

  • Prof. George J. Hirasaki, Department of Chemical and Biomolecular Engineering, Rice University, United States of America
Shih-Yu Tseng
 

Shih-Yu Tseng

PhD Student

Julian  Fischer
 

Julian Fischer

PhD Student

Thomas Sottmann
Apl. Prof. Dr.

Thomas Sottmann

Professor

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