Tamara Schad

Abstract

Oberflächen von historischen Kunst- und Kulturgütern sind häufig verschmutzt. Die Reinigung dieser Objekte ist sehr schwierig, da für unterschiedliche Oberflächen jeweils ein spezielles Reinigungskonzept benötigt wird, um Verschmutzungen zu entfernen ohne das Kunstwerk zu beschädigen. Der sparsame Einsatz von Lösungs- und Reinigungsmitteln stellt Restaurator:innen dabei immer wieder vor große Herausforderungen. Daher sollte eine neue, innovative und schonende Reinigungsmethode auf Basis von Schäumen entwickelt werden, um empfindliche und schwer zugängliche Oberflächen schonend zu reinigen. Tatsächlich kann durch die physikalischen Reinigungsmechanismen des Schaums die Menge des Reinigungsmittels um bis zu 90 % reduziert werden. Der entwickelte Reinigungsschaum wurde zuerst auf Glasmodelloberflächen getestet und anschließend auf den historischen Kutschen im Marstallmuseum im Schloss Nymphenburg angewendet. Die Reinigung dieser historischen, vergoldeten Oberflächen mit Schäumen war so erfolgreich, dass als Glanzstück des Projekts der Krönungswagen von Kaiser Karl VII. vollständig mit Schaum gereinigt wurde.

Abstract

In this study, we present a new method for the detection of lipase. Lipase is an enzyme used as biomarker to monitor medical conditions like pancreatitis or to show the presence of biofilms. Traditionally, detecting lipase required specialized labs and equipment for which one has limited access, especially in less developed regions. Our detection method is based on changes in foam production of lipase-responsive foaming surfactant. Upon addition of the lipase, the ester-linkage of the lipase-responsive surfactant is cleaved which transforms the initially good foaming surfactant into non-foaming molecules so that no foam can be produced anymore. The read-out mechanism for the detection of lipase is the disappearance of foam production by mechanical agitation, i.e., there is a direct link between foam production and lipase activity. Our liquid foam detection method has distinct advantages compared to traditional methods, as it eliminates the need for specialized equipment or the use of markers like fluorescence: the change of foam production is detected directly by naked eyes. The method described here has the potential to be used as a simple fast screening method and to be combined with high-throughput readout systems.

Abstract

We developed a new, innovative foam-based cleaning method with which the amount of detergent can be reduced by up to 90%. In addition, foams generate physical cleaning mechanisms, namely imbibition and wiping. The combination of imbibition and wiping is so efficient that it is sufficient to simply let the foam sit on the surface for a while before removing it by vacuuming. No additional mechanical action is needed! This publication describes how we managed to clean the historic carriages of kings and emperors of past centuries in the “Marstallmuseum” in Nymphenburg Palace in cooperation with the “Bavarian Administration of State-Owned Palaces, Gardens and Lakes”.

Abstract

Abstract Liquid foams of intermediate stability have been shown to be very efficient in the cleaning of sensitive surfaces because of the synergy between imbibition and foam decay. While we quantified these mechanisms for contaminations with liquid oils in our previous work, we show here their extension to oils containing soot particles in an effort to simulate increasingly realistic contaminations. Using foams with a wide range of liquid fractions and with different stabilities, we show that the main cleaning mechanisms remain very similar, with the oil entraining the soot particles. However, we find much less efficient soot removal when the liquid channels of the foams are small enough to hinder efficient transport of the soot particles.

Abstract

Hypothesis Foamed surfactant solutions can clean surfaces! We hypothesise that the cleaning efficiency depends on the liquid fraction and on the stability of the foam. We also hypothesise that the cleaning efficiency is the better the smaller the average bubble size is. Experiments The double syringe technique was used to generate foams with varying liquid fractions but the same, very small bubble sizes with and without perfluorohexane in the gas phase. We performed cleaning tests in which the foams were applied to glass substrates contaminated with a fluorescent oil. Findings We found that unstable foams clean better than stable foams. Three cleaning mechanisms were identified: (1) imbibition at low liquid fractions, (2) wiping, i.e., shifting of the contact line between oil, foam and glass, at all liquid fractions, and (3) drainage at high liquid fractions. The change of the liquid fraction and of the foam stability lead to different combinations of these mechanisms and thus to different cleaning results.

Abstract

On the basis of previous results revealing that intersurfactant H-bonds improve foam stability, we now focus on how foams stabilized by two different N-acyl amino acid surfactants are affected by different salts (NaF, NaCl, NaSCN), which can promote or break intersurfactant H-bonds. The chosen surfactants, namely, sodium N-lauroyl sarcosinate (C12SarcNa) and sodium N-lauroyl glycinate (C12GlyNa), differ only by one methyl group at the nitrogen of the amide bond that blocks intersurfactant H-bonds in the case of C12SarcNa. The salts were chosen because they are kosmotropic (NaF), chaotropic (NaSCN), and in between (NaCl) and thus influence the formation of an H-bond network in different ways. Surface tension measurements showed that the addition of salts decreased the cmcs of both surfactants and increased the packing density, as expected. Moreover, in presence of the salts, the head groups of the H-bond forming surfactant C12GlyNa were more tightly packed at the surface than the C12SarcNa head groups. The effect of the salts on foam stability was studied by analysis of the foam height, the foam liquid fraction, and by image analysis of the foam structure. As expected, the salts had no significant effect on foams stabilized by C12SarcNa, which is unable to form intersurfactant H-bonds. In contrast, the stability of C12GlyNa-containing foams followed the trend NaF > NaCl > NaSCN, which is in agreement with NaF promoting and NaSCN breaking intersurfactant H-bonds. Surface rheology measurements allowed us to correlate foam stability with surface elasticity. This study provides new insights into the importance of H-bond promoters and breakers, which should be used in the future design of tailor-made surfactants.